Yes but not using the UI. Instead, you can use the net user command with the /times switch to set and display the logon hours for a user account. Type net help user for more info.
Mitch Tulloch is lead author for the Windows Vista Resource Kit from Microsoft Press, which is THE book for IT pros who want to deploy, maintain and support Windows Vista in mid- and large-sized network environments. Mitch is also the author of Introducing Windows Server 2008, the first book from Microsoft Press about the exciting new server platform. For more information on these and other books written by Mitch, see www.mtit.com.